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Compared to what? Air? Air is 78% Nitrogen, are you saying you can feel the extra 22%??
Not trying to yank your chain, I am more pessimistic than maybe I should be.
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OK, I was hoping someone else would come up with the facts, so I wouldn't have to do my 2-finger typing act, but to no avail. LOL
Yes, pure air is made up of the ingredients below, and several other minor ones.
Nitrogen -- N2 -- 78.084%
Oxygen -- O2 -- 20.9476%
Argon -- Ar -- 0.934%
Carbon Dioxide -- CO2 -- 0.0314%
Neon -- Ne -- 0.001818%
Methane -- CH4 -- 0.0002%
Helium -- He -- 0.000524%
But, and here is the important fact, the air we put into our tires also contains water vapor. The water vapor is the problem. If you could fill your tires with absolutely dry air, there would be little or no performance change over nitrogen alone.
The water vapor heats up and leaks out of the tire faster than pure N does. It affects the tire pressure variation depending on how much water was in the compressed air on the day you topped off a tire. Humid day, dry day, cold day, hot day?
Using N out of a bottle or nitrogen generator will give you a stable , dry gas that has a molecule larger than oxygen. It is the gas least likely to leak out of a tire over time.
It is entirely feasible that if you filled your tire with air having a high moisture content, that the pressure in that tire could be higher than the tires with pure N. Possible problems are obvious.
I don't sell the stuff, LOL, I just saw the difference in my Expy when I got Michelins from Costco and a free nitrogen fill. They stayed at 35 psi for 4-5 months, using a digital tire gauge. When they dropped to 33 I would fill them up at Costco. I was topping off the factory tires at least once a month or more.
Here is a realistic opinion of nitrogen.
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Do be aware though when people claim that just filling the tire with nitrogen will increase gas mileage. At the low pressures tires hold there is little difference between a properly inflated nitrogen tire and a tire properly inflated with air. Both will get the same gas mileage. The big savings is in the fact that the pressure change in a nitrogen filled tire is slower, and since most people tend not to check their tire pressure on a monthly basis, this can save you in fuel costs.
So, if you're offered the option to have your tires filled with nitrogen, and it's free or is at low cost, then it can be worth it in fuel savings caused by your tires being properly inflated longer. If they want to charge you more than you can afford then take a pass, but make sure you check your air pressure on a regular basis or you will end up paying for it at the pump.
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